Isomers are molecules or polyatomic ions with identical molecular formula, meaning they have the same number of atoms of each element, but distinct arrangements of atoms in space/Chapters/Chapter_5%3A_Properties_of_Compounds/5.1%3A_Isomers). Isomerism refers to the existence or possibility of isomers. Isomers do not necessarily share similar chemical or physical properties. There are two main forms of isomerism: structural or constitutional isomerism, in which bonds between the atoms differ; and stereoisomerism or spatial isomerism, in which the bonds are the same but the relative positions of the atoms differ/Chapters/Chapter_5%3A_Properties_of_Compounds/5.1%3A_Isomers).