Ice floats on water because it is less dense than liquid water. When water freezes, its molecules form a crystal lattice structure held together by hydrogen bonds, creating more open space between molecules than when the water is in its liquid form. This expanded structure means ice occupies more volume and consequently has a lower density than liquid water, allowing it to float.
Water is unusual compared to most substances because solids are typically denser than their liquid forms. In ice, the hydrogen bonds are rigid and hold molecules farther apart, whereas in liquid water, the hydrogen bonds flex and allow molecules to pack more closely. This unique property is crucial for the environment since floating ice insulates aquatic life beneath frozen lakes and oceans and affects global climate systems.
In summary, ice floats because it has a crystal lattice arrangement that takes up more space and lowers its density relative to liquid water.